|
|
7,2,2''-trihydroxy-4,5''-methylenedioxyisoflav-3-ene + O2 + NADPH + H+ <=> (3R,4R)-7,2,4,2''-tetrahydroxy-4,5''-methylenedioxyisoflav-3-ene + H2O + NADP+
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-18746
|
|
|
|
(3R,4R)-3-(6-hydroxy-1,3-benzodioxol-5-yl)-3,4-dihydro-2H-chromene-4,7-diol <=> 7,2''-dihydroxy-4,5''-methylenedioxyisoflav-3-ene + H2O
|
4.2.1
|
–
|
| |
MetaCyc:
RXN-16376
|
|
|
|
(3R,4R)-7,2,4,2''-tetrahydroxy-4,5''-methylenedioxyisoflav-3-ene <=> (+)-6a-hydroxymaackiain + H2O
|
4.2.1
|
–
|
| |
MetaCyc:
RXN-16377
|
|
|
|
S-adenosyl-L-methionine + (+)-6a-hydroxymaackiain <=> H+ + (+)-pisatin + S-adenosyl-L-homocysteine
|
2.1.1.270
(+)-6a-hydroxymaackiain 3-O-methyltransferase
|
–
|
| |
BRENDA:
BR49300
KEGG:
R07750
MetaCyc:
RXN-4002
SABIO-RK:
14605
|
|
|
|
(-)-maackiain <=> (+)-maackiain
|
not assigned
|
–
|
| |
MetaCyc:
RXN-2054
|
|
|
|
(+)-maackiain + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (+)-6a-hydroxymaackiain + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-4561
|
|
|
|
7,2''-dihydroxy-4,5''-methylenedioxyisoflav-3-ene + H2O <=> 7,2,2''-trihydroxy-4,5''-methylenedioxyisoflav-3-ene
|
4.2.1
|
–
|
| |
MetaCyc:
RXN-18745
|
|
